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導師隊伍
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地址:湖北省荊州市荊州區南環路1號   電話:0716-8060650

向景

發布時間:2020-09-15 09:51:39閱讀次數:

     

                                 

向景 

說明: 穿西裝戴眼鏡的男人描述已自動生成

職稱:教授

博導/碩導:博士生導師

學科專業:應用化學

研究方向:激發態反應活性、磁性材料、光學材料

聯系方式:[email protected]

博士,教授,博士生導師,20112月畢業于香港城市大學生物與化學系,20109月—20122月在香港城市大學從事研究員(Research Fellow)工作,現任教于beat365。2013年入選湖北省“楚天學者”計劃“楚天學子”;2016年入選香港‘求搓學者’;2017年湖北省‘杰青’;2019年入選為長江大學‘長江人才計劃’杰出人才。申請人目前在nature子刊《Communications Chemistry.》、RSC旗艦雜志《Chem. Sci.》以及《Carbohydrate Polymers》、《Chem. Commun.》、《Chem. Eur. J》、《Inorg. Chem.》、《Inorg. Chem. Front.》、《Dalton Trans.》、《Organometallics》、《RSC Advances》、《Frontier in chemistry》、《Eur. J. Inorg. Chem.》、《Polyhedron》等共發表SCI收錄文章70多份,其中有6份論文被nature index索引。主要的研究方向在與生物體系中酶的結構或功能相似的模型配合物、含順磁RuIII/OsIII的異核配合物的合成及磁性研究、RuII/OsII/CuI二亞胺配合物的合成及光物理化學性質研究、可見光驅動的有機底物的催化氮化反應等研究領域有多年的研究經驗。

個人簡歷

1999.092003.07 長江大學,高分子材料,學士

2003.092006.07 汕頭大學,應用化學,碩士

2007.092011.03 香港城市大學,應用化學,博士

2010.072012.03香港城市大學,應用化學,Research Fellow

2012.032019.01長江大學,副教授

2019.01—至今    長江大學,教授

2020.012020.12 香港大學,高級訪問學者

主要研究項目

●國家自然科學青年項目(21201023):含氰根、氰氨根、疊氮酸根和胍的順磁的釕、鋨的配合物構筑的新型分子基磁性材料,合同經費23萬,2013.1-2015.12,主持

●國家自然科學基金面上項目(21771026):含配位胍及衍生物的合成與反應活性研究:一種新型的一氧化氮(NO),合同經費65萬,2018.1-2021.12,主持

●湖北省自然科學基金項目(‘杰青’項目)(2018CFA047):新型的可控的NO釋放藥物的合成與性能研究,合同經費20萬,2018.1-2020.12,主持

代表性成果

學術論文

1. Jing Xiang, * Min Peng, Yi Pan, Li-Juan Luo, Shun-Cheung Cheng, Xin-Xin Jin, Shek-Man Yiu, Wai-Lun Man, Chi-Chiu Ko, Kai-Chung Lau, and Tai-Chu Lau*,Visible Light-Induced Oxidative N-dealkylation of Alkylamines by a Luminescent Osmium(VI) Nitrido Complex, Chem. Sci. 2021, 12,14494.

2. Jing Xiang,* Jiang Zhu, Miaomiao Zhou, Lu-Lu Liu, Li-Xin Wang, Min Peng, Bi-Shun Hou, Shek-Man Yiu, Wai-Pong To, Chi-Ming Che,* Kai-Chung Lau,* and Tai-Chu Lau*,Oxidative C-O bond cleavage of dihydroxybenzenes and conversion of coordinated cyanide to carbon monoxide by a luminescent Os(VI) cyanonitrido complex, Chem. Commun., 2022,58, 7988-7991.

3. Min Peng, Xiao-Fan Wu, Li-Xin Wang, Si-Huai Chen, Jing Xiang,* Xin-Xin Jin, Shek-Man Yiu, Bing-Wu Wang,* Song Gao,* Tai-Chu Lau*, Slow Magnetic Relaxation in High-Coordinate Co(II) and Fe(II) Compounds bearing Neutral Tetradentate Ligands,Dalton Trans., 2021, 50, 15327.

4. Qian-Qian Su, Qiong Yuan, Xiao-Fan Wu, Si-Huai Chen,Jing Xiang, * Xin-Xin Jin, Li-Xin Wang, Bing-Wu Wang, Song Gao*and Tai-Chu Lau*, Slow magnetic relaxation in structurally similar mononuclear 8-coordinate Fe(II) and Fe(III) compounds, Chem. Commun., 2021, 57, 781-784.

5. Li-Xin Wang, Jing Xiang, Chuan-Hua Li, Chi-Fai Leung* and Jing Xiang*, Recent Advances on the Applications of Luminescent Pb2+-Containing Metal–Organic Frameworks in White-Light Emission and Sensing, Frontier in chemistry, 2021, 9, 636431. (MINI REVIEW)

6. Xu Zhang, Lanxiang Dai, Pengfei Li, Ting Wang, Liting Qin, Jing Xiang*, Huilin Chang, Characterization of hydrophobic interaction of galactomannan in aqueous solutions using fluorescence-based technique,Carbohydrate Polymers, 2021267, 118183.

7. Qian-Qian Su, Kun Fan, Xin-Da Huang, Jing Xiang,*Shun-Cheung Cheng, Chi-Chiu Ko, Li-Min Zheng,* MohamedallyKurmood and Tai-Chu Lau*, Field-induced slow magnetic relaxation in low spin S = 1/2 mononuclear osmium(V) complexes, Dalton Trans., 2020, 49, 4084–4092.

8. Li-Juan Luo, Qian-Qian Su, Shun-Cheung Cheng,Jing Xiang,* Wai-Lun Man, Wen-Ming Shu,Ming-Hua Zeng, Shek-Man Yiu, Chi-Chiu Ko,* and Tai-Chu Lau*Tunable Luminescent Properties of TricyanoosmiumNitrido Complexes Bearing a Chelating O^N Ligand,Inorg. Chem.2020, 59, 4406?4413.

9. Xin-Xin Jin, Tian Li, Dong-Po Shi, Li-Juan Luo, Qian-Qian Su,Jing Xiang, * Hai-Bing Xu, Chi-Fai Leung and Ming-Hua Zeng, Luminescent phosphine copper(I) complexes with various functionalized bipyridine ligands: synthesis, structures, photophysics and computational study, New J. Chem., 2020, 44, 13393—13400.

10. Jing Xiang*, Xin-Xin Jin, Qian-Qian Su, Shun-Cheung Cheng, Chi-Chiu Ko,* Wai-Lun Man, MinyingXue, Liangliang Wu, Chi-Ming Che,* Tai-Chu Lau,*Photochemical nitrogenation of alkanes and arenesby a strongly luminescent osmium(VI) nitridecomplex,Communications Chemistry, 2019,2, 40.

11. Pui-Yu Ho, Shun-Cheung Cheng, Shek-Man Yiu, Vonika Ka-Man Au,Jing Xiang,*Chi-Fai Leung*and Chi-Chiu Ko*The Important Role of Coordination Geometry on Photophysical Properties of Blue-green Emitting Ruthenium(II) Diisocyano Complexes Bearing 2-Benzoxazol-2-ylphenolate,Inorg. Chem.2019, 58, 11372?11381.

12. Jing Xiang,*Qian-Qian Su, Li-Juan Luo, and Tai-Chu Lau* Synthesis and Reactivity of an Osmium(III) Aminoguanidine Complex,Dalton Trans., 2019, 48, 11404.

13. Jing Xiang, * Shun-Cheung Cheng, Xin-Xin Jin, Qian-Qian Su,Xin Zhou,Wing-Kin Chu, Chi-Fai Leung and Chi-Chiu KoPolynuclear Cu(I) and Ag(I) phosphine complexescontaining multi-dentate polytopic ligands:syntheses, crystal structures andphotoluminescence propertiesDalton Trans., 2019, 48, 741.

14. Qian-Qian Su, Kun Fan, Xin-Xin Jin, Xin-Da Huang, Shun-Cheung Cheng, Li-Juan Luo, Yao-Jie Li, Jing Xiang, *Chi-Chiu Ko,Li-Min Zheng,Tai-Chu Lau,Syntheses, Crystal Structures and Magnetic Properties of a Series of Luminescent Lanthanide Complexes Containing Neutral Tetradentate Phenanthroline-amide Ligands.Inorg. Chem. Front.2019, 6,1442.

15. Xin-Xin Jin, Xiao-Xiang Chen, Jing Xiang,* Yun-Zhou Chen, Li-Hui Jia, Bing-Wu Wang,* Shun-Cheung Cheng, Xin Zhou, Chi-Fai Leung,* and Song Gao,*Slow Magnetic Relaxation in a Series of Mononuclear 8?CoordinateFe(II) and Co(II) Complexes,Inorg. Chem.2018, 57, 3761?3774.

16. C.-F. Leung, S.-C. Cheng, Y. Yang,J. Xiang, S.-M. Yiu,C.-C. Ko and T.-C. LauEfficient photocatalytic water reduction by acobalt(II) tripodal iminopyridine complexCatal. Sci. Technol., 2018,8, 307.

17. J.Xiang,*J.-J. Liu, X.-X. Chen, L.-H. Jia,F. Yu, B.-W. Wang,S. Gao, T.-C. Lau, Slow magnetic relaxation in a mononuclear8-coordinate Fe(II) complex,Chem. Commun., 2017, 53, 1474-1477.

18. J.Xiang,*Qian Wang, Shek-Man Yiu, Tai-Chu Lau, Dual Pathways in the Oxidation of an Osmium(III) GuanidineComplex. Formation of Osmium(VI) Nitrido and Osmium NitrosylComplex,Inorg. Chem.2017, 56, 2022?2028.

19. L.-L. Hu, C. Shen, W.-K. Chu,J.Xiang,* Fei Yu, Ge Xiang, Yan Nie,C.-L. Kwok, C.-F. Leung, C.-C. Ko, Synthesis, structures and photophysical properties of Cu(I) phosphinecomplexes with various diimine ligands, Polyhedron2017, 127, 203–211.

20. J. Xiang, Q. Wang, S.-M.Yiu, W.-L. Man, H.-K.Kwong, T.-C. Lau, Aerobic Oxidation of an Osmium(III) N?Hydroxyguanidine ComplexTo Give Nitric Oxide, Inorg. Chem. 2016, 55, 5056?5061.

21. J.Xiang,*C. Shen, S.-C. Cheng, F. Yu, W.-K. Chu,H. Feng, S.-M.Yiu, C.-C. Ko, C.-F. Leung,Luminescence behaviour of Pb2+-basedcage-containing and channel-containing porouscoordination polymers,Dalton Trans., 2016, 45, 16134–16138.

22. F. Yu, W.-K. Chu, C. Shen, Y. Luo, J. Xiang,* S.-Q. Chen,C.-C. Ko, T.-C. Lau, Luminescent Carbonyl Hydrido Ruthenium(II) DiimineCoordination Compounds: Structural, Photophysical, andElectrochemical Properties, Eur. J. Inorg. Chem.2016, 3892–3899.

23. F. Yu, C. Shen, T. Zheng, W.-K. Chu,J.Xiang,* Y. Luo,C.-C. Ko, Z.-Q. Guo, T.-C. Lau, Acid–Base Behaviour in the Absorption and Emission Spectra ofRuthenium(II) Complexes with Hydroxy-Substituted Bipyridineand Phenanthroline Ligands,Eur. J. Inorg. Chem. 2016, 3641–3648.

24. Chang Shen, Fei Yu, Wing-Kin Chu, Jing Xiang,* Peng Tan, Ya Luo, Hua Feng, Zheng-Qing Guo,* Chi-Fai Leung* and Tai-Chu Lau, Synthesis, structures and photophysical properties of luminescent cyanoruthenate(II) complexes with hydroxylated bipyridine and phenanthroline ligands, RSC Adv.,2016, 6,87389–87399.

25. Jing Xiang,* Li-Hui Jia, Hui-Sheng Wang, Shie-Ming Peng, Song Gao,* and Tai-Chu Lau*, Synthesis, Crystal Structures, and Magnetic Properties of HeterodimetallicRuIII–3d Coordination Compounds Based on a Meridional Tricyanoruthenium(III) Building Block, Eur. J. Inorg. Chem. 2015, 1065–1073.

26. Zheng-nengJin , Hua-jiang Jiang , Jia-shou Wua, Wei-zhong Gong, Yue Cheng, Jing Xiang,Qi-Zhong Zhou, Synthesis of 2-heterocyclic substituted pyrrolidines by coppercatalyzed domino three-component decarboxylative coupling and cyclization reactions, Tetrahedron Letters 2015, 56, 2720–2723.

27. J. Xiang, W.-L. Man, J.-F. Guo, S.-M.Yiu, G.-H. Lee, S.-M. Peng,G.-C. Xu, S. Gao and T.-C. Lau,A novel tricyanoruthenium(III) building block for the construction of bimetallic coordination polymers,Chem. Commun.,2010, 46, 6102-6104.

28. J. Xiang, L.-H. Jia, W.-L. Man, K. Qian, S.-M.Yiu, G.-H. Lee,S.-M. Peng,S. Gao and T.-C.Lau,Novel heterobimetallic ruthenium(III)–cobalt(II) compounds constructedfrom trans-[RuIII(Q)2(CN)2] (Q = 8-quinolinolato): synthesis,structures and magnetic properties, Chem. Commun.,2011, 47, 8694–8696.

29. J. Xiang, W.-L. Man, S.-M.Yiu, S.-M. Peng, and T.-C. Lau, Reaction of an Osmium(VI) Nitrido Complex with Cyanide: Formation andReactivity of an Osmium(III) Hydrogen Cyanamide Complex, Chem. Eur. J.,2011, 17, 13044-13051.

30. J. Xiang, L. T.-L. Lo, C.-F. Leung, S.-M.Yiu, C.-C. Ko, and T.-C. Lau, Synthesis, Structures, and Photophysical Properties of Ruthenium(II)Quinolinolato ComplexesOrganometallics, 2012, 31, 7101?7108.

31. J. Xiang, L.-H. Jia, W.-L. Man, K. Qian, G.-H. Lee, S.-M. Peng, S.-M.Yiu,S. Gao and T.-C. Lau, A novel triazidoruthenium(III) building block for the construction of polynuclear compounds,Dalton Trans.2012, 41, 5794-5798.

32. J. Xiang, L.-H. Jia, B.-W. Wang, S.-M.Yiu, S.-M. Peng,W.-Y. Wong, S. Gao and T.-C. Lau, The synthesis, structures and magnetic properties of polynuclear RuIII-3d (3d = MnII/III, NiII, CuII) compounds based on [RuIII(Q)2(CN)2],Dalton Trans.2013, 42, 3876-3887.

33. C.-F. leung, S.-M. Yiu, J. Xiang and T.-C. Lau, Addition of [CH(CN)2]and [TCNE]?–to RuVI≡N bearing 8-quinolinolato ligands,Chem. Commun., 2010, 46,7575-7577.

34. C.-F. Leung, S.-M. Ng,J. Xiang, W.-Y. Wong, Michael H.-W. Lam,C.-C. Ko, and T.-C. Lau,Synthesis and Photophysical Properties of Ruthenium(II) IsocyanideComplexes Containing 8-Quinolinolate Ligands,Organometallics, 2009, 28, 5709–5714.

35. H.-K.Kwong, W.-L. Man, J. Xiang, W.-T. Wong, and T.-C. Lau, Reaction of a (Salen)ruthenium(VI) Nitrido Complex with Isocyanide,Inorg. Chem. 2009, 48, 3080-3086.

36. W.-L. Man, H.-K.Kwong, William W. Y. Lam, J. Xiang, T.-W. Wong, W.-H. Lam,W.-T. Wong, S.-M. Peng, and T.-C. Lau,General Synthesis of (Salen)ruthenium(III) Complexes via N···NCoupling of (Salen)ruthenium(VI) NitridesInorg. Chem. 2008, 47, 5936-5944.


 

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