報告題目：微孔材料的結構確定

報 告人：孫俊良 北京大學 研究員

時 間：2019年9月24日上午9:40

地 點：長江大學東校區文科大樓910

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2019年9月19日

孫俊良,研究員,工作于北京大學化學與分子工程學院，2001年畢業于北京大學，獲學士學位，后師從北京大學原校長林建華教授，2006年獲得博士學位。孫俊良研究員是北京大學化學與分子工程學院無機固體材料化學組組長，中國晶體學會秘書長，黨委書記。主要從事結構確定方法的發展（包括單晶/粉末衍射和三維電子衍射技術）和微孔材料的合成及其結構解析。國際沸石協會承認的245個沸石結構中，孫俊良研究員參與其中9個的結構確定，目前還有4個在申請中。他還發展了一系列新的結構確定方法（旋轉電子衍射、電子衍射與粉末衍射結合、從正空間確定調制結構的超空間群等）。近年來在相關領域以第一作者或通信作者在Nature(1篇)、Science(1篇)、Angew.Chem.(4篇)、JACS(4篇)、Adv. Energy Mater.(2篇)、Nature Comm. (3篇) 、Acc.Chem.Soc.(1篇)等雜志發表論文100余篇。這些工作得到國際同行的充分認可，被多次邀請做學術報告，如2013中國分子篩年會和2015年全國無機化學會議的大會報告、2014和2017年國際晶體學年會的邀請報告等。由于在孔材料合成和結構確定方面的突出貢獻，2017年獲得首屆中國分子篩青年獎。2018年獲中國石化前瞻性基礎性研究科學獎一等獎。

Publications of Junliang Sun

(All publications and reviews are in peer-reviewed international journals)

H-index on Scopus: 42

Original publications

1. Rong-Ran Liang, Shun-Qi Xu, Lei Zhang, Ru-Han A, Fu-Zhi Cui, Qiao-Yan Qi, Junliang Sun,* Xin Zhao* Rational design of crystalline two-dimensional frameworks with highly complicated topological structures Nature Comm. 2019 in press.

2. Chuanfu Wang*, Lei Zhang, Xin Huang, Yufei Zhu, Gang(Kevin) Li, Qinfen Gu, Jingyun Chen, Linge Ma, Xiujie Li, Qihua He, Junbo Xu, Qi Sun, Chuqiao Song, Mi Peng, Junliang Sun*, and Ding Ma* Maximizing sinusoidal channels of HZSM-5 for high shape-selectivity to p-xylene Nature Comm. 2019 in press.

3. Hongliang Chen, Mingliang Li, Zheyu Lu, Xiaoge Wang, Junsheng Yang, Zhe Wang, Fei Zhang, Chunhui Gu, Weining Zhang, Yujie Sun, Junliang Sun*, Wenguang Zhu*, Xuefeng Guo* Multistep nucleation and growth mechanisms of organic crystals from amorphous solid states Nature Comm. 2019 in press.

4. Chao Gao, Jian Li, Sheng Yin, Guiqing Lin, Tianqiong Ma, Yi Meng, Junliang Sun* and Cheng Wang* Designed Synthesis of Isostructural 3D Covalent Organic Frameworks: Toward Modification of Pore Environment Angew Chem. Int. Ed. 2019, 58, 9770-9775.

5. Xiaoge Wang, Yihan Shen, Rongli Liu, Xiaolong Liu, Cong Lin, Dier Shi, Yanping Chen, Fuhui Liao, Jianhua Lin, Junliang Sun* Elucidation of correlated disorder in zeolite IM-18 Acta Cryst., 2019, B75, 333-342.

6. Jian Li, Cong Lin, Yuxin Min, Youyou Yuan, Guobao Li, Sihai Yang, Pascal Manuel, Jianhua Lin, Junliang Sun* Discovery of complex metal oxide materials by rapid phase identification and structure determination J. Am. Chem. Soc. 2019, 141,4990. DOI: 10.1021/jacs.9b00093

7. Yanping Chen, Ning Ma, Shiliang Huang,* Xin Du, Fuhui Liao, Yuexiang Zhu, Junliang Sun*, Yingxia Wang*. A new interrupted zeolite PKU-26 and its transformation to a fully four-connected zeolite PKU-27 upon calcination. Chem. Eur. J. 2019, 25，3219-3223. DOI: 10.1002/chem.201805972 (hot paper)

8. Dier Shi, Le Xu,* Pohua Chen, Tianqiong Ma, Cong Lin, Xiaoge Wang, Diming Xu and Junliang Sun* Hydroxyl free radical route to the stable siliceous Ti-UTL with extra-large pores for oxidative desulfurization Chem. Comm. 2019, 55, 1390-1393. DOI: 10.1039/c8cc09225g

9. Yi Luo, Stef Smeets, Zhendong Wang*, Junliang Sun* and Weimin Yang* Synthesis and structure determination of SCM-15: a 3D large pore zeolite with interconnected straight 12×12×10-ring channels Chem. Eur. J. 2019, 25, 2184-2188. DOI: 10.1002/chem.201805187

10. Yaming Qiu, Lei Zhang, Lingmei Liu, Cong Lin, Le Xu, Jian Li, Youyou Yuan, Xin Du, Yu Han * and Junliang Sun* Photoinduced synthesis of Bi2O3 nanotubes based on oriented attachment J. Mater. Chem. A, 2019, 7, 1424-1428. DOI: 10.1039/c8ta09921a

11. Yaming Qiu, Cong Lin, Jian Li, Lei Zhang, Le Xu, Yifang Zhao, X. Xin Du, Ligang Wang, Fengjuan Pan, Fuhui Liao, and Junliang Sun* Discovery of Layered Indium Hydroxide via a Hydroperoxyl Anion Coordinated Precursor at Room Temperature Chem. Eur. J. 2019, 24, 15491-15494. DOI: 0.1002/chem.201803093 (hot paper)

12. Huimin Ding^#, Jian Li^#, Guohua Xie, Guiqing Lin, Rufan Chen, Zhengkang Peng, Chuluo Yang, Baoshan Wang, Junliang Sun*, and Cheng Wang* An AIEgen-Based 3D Covalent Organic Framework for White Light-Emitting Diodes Nature Comm. 2018, 9, 5234. DOI : 10.1038/s41467-018-07670-4

13. Tianqiong Ma^#, Eugene A. Kapustin^#, Shawn X. Yin, Lin Liang, Zhengyang Zhou, Jing Niu, Li-Hua Li, Yingying Wang, Gaifen He, Jie Su, Jian Li, Xiaoge Wang, Wei David Wang, Wei Wang^*, Junliang Sun*, Omar M. Yaghi* Single-crystal X-ray diffraction structures of covalent organic frameworks Science 2018, 361, 48-52.

14. Xing Huang, Haisheng Li, Zeyi Tu, Liyao Liu, Xiaoyu Wu, Jie Chen, Yingying Liang, Ye Zou, Yuanping Yi, Junliang Sun,* Wei Xu,* and Daoben Zhu* Highly Conducting Neutral Coordination Polymer with Infinite Two-Dimensional Silver?Sulfur Networks J. Am. Chem. Soc. 2018, 140, 15153-15156.

15. Junzhong Lin, Magdalena O. Cichocka, Fei Peng, Taimin Yang, Junliang Sun* Hierarchical Shell-like ZSM-5 with tunable porosity synthesized using a dissolution-recrystallization approach Chem. Eur. J. 2018, 24, 14974-14981.

16. Junzhong Lin, Taimin Yang, Cong Lin, Junliang Sun* Hierarchical MFI zeolite synthesized via regulating the kinetic of dissolution-recrystallization and their catalytic properties Catalysis Comm. 2018, 115, 82-86.

17. Mirding Mutailipu, Min Zhang, Hongping Wu, Zhihua Yang, Yihan Shen, Junliang Sun*, Shilie Pan* Ba₃Mg₃(BO₃)₃F₃ polymorphs with reversible phase transition and high performances as ultraviolet nonlinear optical materials Nature Comm. 2018, 9, 3089. DOI: 10.1038/s41467-018-05575-w

18. Tianqiong Ma, Jian Li, Jing Niu, Lei Zhang, Ahmed S. Etman, Cong Lin, Dier Shi, Pohua Chen, Li-hua Li, Xin Du, Junliang Sun,* and Wei Wang* Observation of Interpenetration Isomerism in Covalent Organic Frameworks, J. Am. Chem. Soc. 2018, 140, 6763-6766. DOI: 10.1021/jacs.8b03169

19. Yonggang Wang^#, Jianjun Ying^#, Zhengyang Zhou^#, Junliang Sun^#, Ting Wen, Yannan Zhou, Nana Li, Qian Zhang, Fei Han, Yuming Xiao, Paul Chow, Wenge Yang, Viktor V. Struzhkin, Yusheng Zhao*, Ho-kwang Mao* Emergent superconductivity in an iron-based honeycomb lattice initiated by pressure-driven spin-crossover Nat. Comm. 2018, 9, 1914. DOI: 10.1038/s41467-018-04326-1

20. Jia Lin, Minliang Lai, Letian Dou, Christopher S. Kley, Hong Chen, Fei Peng, Junliang Sun, Dylan Lu, Steven A. Hawks, Chenlu Xie, Fan Cui, A. Paul Alivisatos, David T. Limmer and Peidong Yang Thermochromic halide perovskite solar cells Nat. Mater. 2018, 17, 261-267.

21. Yifang Zhao, Jian Li, Cong Lin, Yaming Qiu, Yanquan Yang, Xiaoge Wang, Fengjuan Pan, Ligang Wang, Jianhua Lin* and Junliang Sun* One-pot synthesis of Cu-modified HNb3O8 nanobelts with enhanced photocatalytic hydrogen production J. Mater. Chem. A, 2018, 6, 10769-10775. DOI: 10.1039/C8TA02766H

22. Yanquan Yang, Jian Li, Youyou Yuan, Fengjuan Pan, Dier Shi, Cong Lin, Xin Du and Junliang Sun* Synthesis and crystal structure of Sr₃Bi₂O₆ and structural change in the strontium-bismuth-oxide system Dalton Trans. 2018, 47, 1888-18894

23. Cong Lin, Fengjuan Pan, Jian Li, Dier Shi, Yanquan Yang, Xin Du, Fuhui Liao, Jianhua Lin, Tao Yang*, and Junliang Sun* An Open-Framework Aluminophosphite with Face-Sharing AlO6 Octahedra Dimers and Extra-Large 14-Ring Channels Cryst. Growth & Des. 2018, 18, 1267-1271

24. Xin Du, Yanquan Yang, Dier Shi, Cong Lin, Yaming Qiu, and Junliang Sun* The construction of a series of hierarchical MWW-type zeolites and their catalytic performances for bulky aldol condensation Microporous & Mesoporous Mater. 2018, 268, 117-124

25. Ahmed S. Etman, Junliang Sun*, R. Younesi* V2O5·nH2O nanosheets and multi-walled carbon nanotube composite as a negative electrode for sodium-ion batteries J. Energy Chem. 2018, 30, 145-151.

26. Le Xu, Lin Zhang, Jian Li, Koki Muraoka, Fei Peng, Hao Xu, Cong Lin, Zihao Gao, Jin-Gang Jiang, Watcharop Chaikittisilp, Junliang Sun*, Tatsuya Okubo and Peng Wu* Crystallization of A Novel Germanosilicate ECNU-16 Provides Insights into the Space-Filling Effect on Zeolite Crystal Symmetry Chem. Eur. J. 2018, 24, 9247-9253. DOI:10.1002/chem.201802087

27. Zhengyang Zhou^#, Yi Qiu^#, Fei Liang^#, Luká? Palatinus, Morgane Poupon, Tao Yang, Rihong Cong, Zheshuai Lin,* Junliang Sun* CsSiB₃O₇: A Beryllium-Free Deep-Ultraviolet Nonlinear Optical Material Discovered by the Combination of Electron Diffraction and First-Principles Calculations Chem. Mater. 2018, 30, 2203-2207.

28. Shiliang Huang, Huijuan Yue, Yanping Chen, Yu Liu, Yuxiang Guan, Xiaodong Zou,* and Junliang Sun* Three-Dimensional Open-Framework Germanate Built From a Novel Ge13 Cluster and Containing Two Types of Chiral Layers Cryst. Growth & Des. 2018, 18, 928-933.

29. Yi Luo, Zhendong Wang*, Junliang Sun,* Yingying Wang, Shaoqing Jin, Bin zhang, Hongmin Sun and Weimin Yang* Facile and green route for the synthesis of SFE borosilicate zeolite and its heteroatom substituted analogues with promising catalytic performance Chem. Eur. J. 2018, 24,306-311.

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